Abstract

A modelling study is made of propylene hydrogenation over platinum-alumina, using extensive kinetic data along with information on the surface species. A comprehensive set of Langmuir-Hinshelwood-Hougen-Watson kinetic models is constructed for this system, and the preferred member is selected by Bayesian estimation along with chemical criteria. A realistic, accurate reaction model is thus determined. Comparisons are also made with earlier models.

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