Abstract
Abstract The kinetics of polymerization of methyl methacrylate (MMA) initiated by the potassium peroxodisulfate (K2S2O8)-malonic acid (MA) redox system catalyzed by Ag(I) was studied in aqueous solution at 35°C. The rate of polymerization (R) was proportional to [MMA]1.4, [K2S2O8]0.27, [MA]0.23, and [Ag+]0.5. The overall energy of activation was calculated to be 13.5 kcal·K−1·mol−1 between 20 and 45°C.
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