Abstract

Iron(III)-1,10-phenanthroline complex obtained, in situ, by direct mixing of iron(III) and 1,10-phenanthroline, oxidizes V(IV). The reaction is markedly accelerated by sodium dodecyl sulphate. The rate-[surfactant] profile exhibits a maximum. The kinetic analysis of the micellar effect has been carried out using Bereazin's approach. The binding constants of 1,10′-phenanthroline and V(IV) have been determined.

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