Abstract
The kinetics of the title reaction was investigated spectrophotometrically in aqueous perchloric acid medium under isolated conditions, ([NH2OH]≫[Fe(III)]). The reaction was found to be first order in iron(III) as well as in the substrate. INcrease in the [H+] ion concentration of the medium were found to decrease the rate of the reaction, while ionic strength has little influence. Kinetic evidence for the formation of a 1∶2 complex between iron(III) and 1,10-phenanthroline has been obtained. Nitrogen was found to be the principal product of oxidation. A plausible mechanism consistent with the observed
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