Abstract

The behavior of Np(V) in concentrated HNO3 solutions containing potassium phosphotungstate K10P2W17O61 (KPW) at various concentrations of HNO3 (1.0–3.0 M) and KPW [(1–5) × 10−3 M] was studied. Under the examined experimental conditions, the final products of Np(V) transformation are Np(IV) and Np(VI). The reaction follows a first-order rate equation with respect to the Np(V) concentration.

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