Abstract
The kinetics of chlorination of benzene with a mixture of sodium peroxide with hydrochloric acid in aqueous acetic acid at 298 K was studied. The chlorination rate is the highest when the AcOH concentration in the binary solvent is 49.4-40.6 mol % and the ratio of the initial cocentrations of water and sodium peroxide, 18.5–20.2. The linear dependences of logk app on the AcOH concentration and [H2O]0/[Na2O2]0 ratio were obtained.
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