Abstract
WHEN a hydrocarbon with N equivalent, exchangeable hydrogen atoms is subjected to protium–deuterium exchange, molecules with 0, 1, . .j. . N deuterium atoms are formed, which we shall denote by … Dj. . and their fractions by … dj … Neglecting isotope effects, the average degree of deuteration σ, expressed by : which changes according to the exponential rate law for exchange1,2.
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