Abstract

The kinetics of hydrolysis of N-phenylbenzohydroxamic acid have been studied in 1.8 to 8.1 mol dm -3 H 2 SO 4 at 55 °C. The rate of reaction increases with increasing concentration of H 2 SO 4 , nearly linearly up to 7.2 mol dm -3 and then increased sharply. The rate maximum was not observed. The effect of temperature on the rate of hydrolysis has been studied. Activation parameters have been calculated. Bimolecular nature of hydrolysis has been supported by Arrhenius parameters, Bunnett-Olsen, Zucker-Hammett hypothesis etc.

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