Abstract
The heterogeneous exchange reaction between cobalt ions in solution and Co3Co(CN)6 2 · 12 H2O has been studied. It is found that the exchange rate increases as the concentration of Co2+ ions in solution decreases. The results show that the exchange rate is controlled by the surface reaction at the solid-liquid interface. The activation parameters Ea, ΔH#, ΔS#, and ΔG# are calculated.
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