Abstract
The thermodynamic parameters of ion exchange have been estimated for HZr2(PO4)3 · H2O and the products of its aliovalent doping. Ion exchange occurs via formation of the (H3O1 − xNax)Zr2(PO4)3 solid-solution series. As in the case of ion exchange on layered zirconium phosphate (Zr(HPO4)2 · H2O), the interdiffusion coefficient and the major interfacial defect generation processes are considerably affected by the contact-solution pH.
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