Abstract
The rate coefficients of H abstraction and OH addition reactions of 2,4,4-trimethyl-1-pentene with OH were determined by both canonical variational transition state theory and conventional transition state theory. The potential energy surfaces were calculated at CCSD(T)/6-311++G(d, p)//BHANDHLYP/6-311(d, p) level and quantum effects were evaluated by the one-dimensional Wigner method and the multidimensional zero-curvature and small-curvature tunneling methods. 2,4,4-Trimethyl-1-pentene contains primary and secondary allylic H abstraction, alkyl, and vinylic H abstraction channels and OH addition into central and terminal carbon atoms channels. The results show that allylic H abstraction channels dominate the overall H abstractions resulting from the lower barriers, in which, primary H abstraction involves indirect channel via a reactant complex and direct channel. Moreover, OH addition reactions into central and terminal carbon atoms all contain Van der Waals reactant complexes, while the latter channel exhibits negative temperature dependence as a result of its submerged barrier. The branching ratio is more than 75% for addition reactions below 500K and more than 80% above 1100K for H abstraction reactions. Rate coefficients of all channels were fitted in terms of a quasi-Arrhenius expression.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.