Abstract
ABSTRACT Cupric chloride leaching is an attractive alternative for the treatment of pyritic refractory gold ores. In this context, the kinetics of pyrite dissolution was studied in cupric chloride solutions containing 4 M NaCl. Pyrite leaching experiments were conducted in a stirred tank reactor for 250 h. The effect of temperature was evaluated at 45°C, 60°C and 75°C, while the effect of [Cu (II)] was evaluated with solutions containing 0.054, 0.252 and 0.512 M. The results showed that the increase in temperature and [Cu (II)] improved the rate of pyrite dissolution. The fraction of pyrite oxidised to sulphate ranged from 52% to 75%. Sulphate formation correlated well with the number of holes and cracks formed on leached pyrite particles. The kinetics of pyrite dissolution fitted well to the shrinking core model with chemical reaction control (T ≤ 60°C and [Cu (II)] ≤ 0.054 M) or mixed control (T > 60°C and [Cu (II)] > 0.054 M). The activation energy was 73.102 kJ/mol and the dependence of [Cu (II)] was proportional to .
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
