Abstract
Temperature-modulated differential scanning calorimetry (DSC) has been used to study the crystallization kinetics of Ti 50Cu 20Ni 30 metallic glass. The method of Matusita and Sakka for the kinetic study of crystallization seems to be still applicable despite the temperature modulation on four various linear heating rates (5, 10, 15 and 20°C/min) as it utilizes fractional crystallization at various temperatures of the crystallization curve in a continuous temperature domain. The modified Kissinger equation, on the other hand, underestimates the activation energy of crystallization as it incorporates particular discrete temperature points, i.e. peak crystallization temperatures at different heating rates.
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