Abstract
The intensity of a variety of mass spectrometric fragmentation processes as function of the decomposition time is reported. As result of the low activation energies, rearrangement reactions are the dominating decomposition processes at long decomposition times (ca. 10 −5 s) whereas direct cleavages are often, but not always favored at short times (ca. 10 −11 s). This is attributed to their “loose” transition state.
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