Abstract
Previous hydrocarbon evolution data were reanalysed to determine improved rate expressions for oil generation from Colorado oil shale under rapid pyrolysis conditions. Contributions from low-molecular-weight gases were subtracted from flame-ionization detector data to obtain the rate of oil generation alone. Equally good fits to the data were obtained using two parallel first-order reactions or a single reaction with an effective reaction order of 1.51. The latter expression was easier to incorporate into global process models. The rate expressions were independent of shale source (Anvil Points or Tract C-a) and particle size (0.5–2.4 mm). The kinetic data were consistent with the previous conclusion that the small incremental oil yield possible for fluidized-bed pyrolysis requires a longer residence time than that estimated by kinetic expressions derived from slow-heating data.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.