Abstract

The rate constants of the reaction of MeI with hydroxide ion at 298-323 K in aqueous isopropanol (isopropanol content 0-30 mol %) were measured. The effects of solvation of the reactants and activated complex were separated. The contributions of particular types of interactions to the solvation of the charged species were calculated. The results were compared with data for three other water-organic solvent systems.

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