Abstract
Self-Assembling systems that rely on non-covalent forces to drive ordering are the subject of intense study. Of particular interest are redox active systems like porphyrins and phthalocyanines that can generate self-assembled monolayers (SAMs) at the solution-solid interface. These offer the potential of creating highly ordered films from the simple process of solution dipping. In recent years, it has become clear that kinetics plays a significant role in determining the structure of these films. However, very little is known about the rates and mechanisms of the formation and stability of these interesting surface layers. In this talk we will present new data and models for the adsorption and desorption kinetics of non-covalent SAMs on gold surfaces. As might be suspected, the adsorption and desorption rates do not follow simple Langmuir behavior. Also, the potential for multilayer growth must be considered.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.