Abstract
AbstractThe mechanism of acid catalyzed decomposition of peroxodisulfate, (S2O) in aqueous perchlorate medium involves the hydrolysis of the species H2S2O8 and HS2O and the homolysis of the species H2S2O8, HS2O and S2O at the OO bond. The overall rate law when 1.4M > [HClO4] > 0.1M is The constants k′ and k″ contain the hydrolysis and homolysis rate constants of HS2O8− and H2S2O8, respectively. With added Ag(I), the acid catalyzed and Ag(I) catalyzed reactions take place independently. Ag(I) catalyzed decomposition appears to involve the species AgS2O (aq).
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