Abstract
We have constructed the pseudoternary phase diagram of surfynol465 + n-butanol + cyclohexane + H2O with k m = 2 (where k m is the weight ratio of surfynol465 to n-butanol) by the water titration method. Electrical conductivity measurements were employed to investigate the microstructures of the single-phase region. In the oil/water microemulsion region, we have measured the hydrolysis reaction rate of 2-bromo-2-methylpropane near and far away from the critical point. It was found that the Arrhenius equation was valid for correlating experimental measurements far away from the critical point but a significant acceleration effect exists near the critical point, which is not consistent with thermodynamic interpretation of Griffiths and Wheeler.
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