Abstract
Rate constants for the reactions of NO{sub 3} with a number of aliphatic mono- and dialkenes and monoterpenes have been determined in a 420 1 reaction chamber at 1-bar total pressure of synthetic air by 298 K with a relative kinetic method. The products of these reactions have been investigated also at 1-bar total pressure of synthetic air with in situ FT-IR spectrometry and gas chromatography. In all cases, the initial formation of thermally unstable nitrooxy-peroxynitrate-type compounds containing the difunctional group -CH(OONO{sub 2})-CH(ONO{sub 2})- has been observed.
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