Abstract
Kinetic study of the deiodination of m-chloroiodobenzene (to chlorobenzene and iodide ion), as effected by sodium or potassium methoxide in methanol, with initiation by thermolysis of azobisisobutyronitrile (AIBN), reveals kinetic orders 1.0 in aryl iodide and 0.5 in AIBN. The reaction is 0.86 order in potassium methoxide, but the dependence of rate on sodium methoxide concentration is less easily stated. Nitrobenzene inhibits the reaction. At high inhibitor concentrations, the kinetic order in nitrobenzene approaches -1 and concomitantly the Kinetic order in AIBN approaches unity
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