Abstract

(3)The aminolysis reaction of carbonyl compounds is one of the most extensively investigated subjects in mechanistic organic chemistry. In this type of reaction, a non-linear Bronsted-type plot showing a break from a large (β = 0.8 ‒ 1.0) to a small (β = 0.1 ‒ 0.3) rate dependence on basicity of the attacking amine is often obtained at p

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