Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of Dimethyl Sulfoxide by N-Chlorosuccinimde in Aqueous Alkaline Medium

Abstract

The ruthenium(III) catalyzed oxidation of dimethyl sulfoxide by N-chlorosuccinimide (NCS) in aqueous alkaline medium is found to occur via substrate-catalyst complex formation followed by the interaction of active species of NCS viz., HOCl and the complex in a slow step to yield the products with regeneration of the catalyst. One of the products, succinimide, retards the rate of reaction. The reaction is first order in [NCS] and [Ru(III)], lower than first order in [DMSO] and of inverse fractional order in [OH-]. A suitable mechanism is proposed and the reaction constants of individual steps involved in the mechanism have been evaluated.