Kinetics and mechanism of removal of methylene blue by adsorption on various carbons—a comparative study

Abstract

The kinetics and mechanism of methylene blue adsorption on commercial activated carbon (CAC) and indigenously prepared activated carbons from bamboo dust, coconut shell, groundnut shell, rice husk, and straw, have been studied. The effects of various experimental parameters have been investigated using a batch adsorption technique to obtain information on treating effluents from the dye industry. The extent of dye removal increased with decrease in the initial concentration of the dye and particle size of the adsorbent and also increased with increase in contact time, amount of adsorbent used and the initial pH of the solution. Adsorption data were modeled using the Freundlich and Langmuir adsorption isotherms and first order kinetic equations. The kinetics of adsorption were found to be first order with regard to intra-particle diffusion rate. The adsorption capacities of indigenous activated carbons have been compared with that of the commercial activated carbon. The results indicate that such carbons could be employed as low cost alternatives to commercial activated carbon in wastewater treatment for the removal of colour and dyes.