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Abstract
Solution polymerization of methylmethacrylate (MMA) initiated by p-acetylbenzylidene triphenylarsonium ylide in dioxane was carried out at 60±0.2 °C up to 10 hrs. in a polymerization tube under a nitrogen atmosphere. The values of the initiator and the monomer exponent were computed as 0.46 and 1.03, respectively. The overall activation energy and kp2/kt were calculated as 53 KJ/mole and 1.19 × 10−2 L/mol·s, respectively for the polymerization.
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