Abstract
The formation of MV•+ radical cations was observed upon the laser flash photolysis of the iron(III) tartrate complex [FeIIITart]+ (1) in the presence of methyl viologen (MV2+). The rate constants of the reactions involving MV•+ were measured. The intramolecular electron trans-fer to form FeII and escape of the organic radical to the solvent bulk upon the photolysis of 1 were proposed.
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