Abstract
toluene sulfonamide (E Merck) was used as received without any further treatment. The solution was prepared in doubly distilled water and was standardized iodometrically. 39,40 Since the solution of chloramine-T is not stable, therefore, the solution was kept in bottles coated black from the outside. The solution of choramine-T, if kept, in dark at refrigerated temperature (~5 oC), the stability is enhanced considerably. Other reagents were either of AnalR or G.R. quality and were used as supplied. Doubly distilled water was employed throughout the kinetic study; second distillation was from alkaline permanganate solution in an all glass assembly. Stoichiometry and Product Analysis. The stoichiometry
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