Abstract
A series of kinetically stabilized trans bis-chelate metal complexes, trans-(CabP,Si)2M (M = Pt 4; M = Pd 7a), bearing bulky o-carboranylphosphine tethers, have been synthesized from the reaction of the phosphinosilanes 2 with d10 metal complexes. In the presence of dimethyl acetylenedicarboxylate (DMAD), the trans isomer 4 thermally rearranges to the thermodynamically favored cis isomer, cis-(CabP,Si)2Pt 5.
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