Abstract

HighlightsThrough facial basicity adjustment, kinetically favorable ZnxNi1-xO@CF electrode was formed with a high density hierarchical structure and three dimensional open pores.The optimal Zn-doping ratio in ZnxNi1-xO@CF has excellent sodium storage and desalination performance (128.9 mg g-1).The mechanism of Na+ intercalation process was studied by electrochemical quartz crystal microbalance with dissipation monitoring in situ test and the activation mechanism of redox-inert Zn-doping on electrode materials was reported.

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