Abstract
用分光光度法研究了二甲亚砜溶液中，氯化铜与ｍｅｓｏ－四（间甲基）苯基卟啉镉（Ⅱ）（Ｃｄ（Ⅱ）Ｐ）亲电取代反应的动力学。讨论了影响反应的因素，ＣｕＣｌ２＋Ｃｄ（Ⅱ）Ｐ←Ｃｕ（Ⅱ）Ｐ＋ＣｄＣｌ２提出了反应机理并进行了验证。用ＡＳＴ２８６微机对实验数据进行非线性最小二乘法拟合，得到拟合曲线及似平衡的平衡常数Ｋ及其它基元步骤的速率常数，ｋ１，ｋ－１，ｋ２。研究了温度对反应的影响，求得似平衡步的△ｒＨ＾ｍ，
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