Abstract
The kinetics of rapid bimolecular reactions involving ClO, X2Π, v= 0, radicals at 298 K have been studied mass spectrometrically using molecular beam sampling from a discharge-flow system. The following rate constants (298 K, cm3 molecule–1 s–1) are reported: [graphic omitted] ClO radicals were found to be unreactive towards a range of singlet ground state molecules, up to 670K.
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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