Abstract

The pressure-jump technique with conductivity detection has been adopted for the kinetic study of crystal growth of sparingly soluble salt. The single relaxation was observed in aqueous suspension of thallium sulfate. The reciprocal relaxation time observed increases linearly with the concentration of crystal. According to the chemical relaxation treatment, the rate constants of crystal growth and dissolution in the suspension of crystal were determined to be 4.6 × 10 -1 mol -1 dm 3 s -1 and 2.1 × 10 -2 s -1, respectively, at 25°C.

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