Abstract
Stability of chloro(octaphenyltetraazaporphinato)indium(III) and chloro(2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diazaporphinato)indium(III) in 90-98 % aqueous sulfuric acid was studied. Kinetic parameters of solvoprotolytic dissociation of the complexes were determined, and a mechanism of the reaction was proposed. Diaza substitution results in more stable complexes than tetraaza substitution. The state of chloro(2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diazaporphinato)indium(III) in a proton-donor medium was studied to show that the acid-base interaction involves one by one two meso-nitrogen atoms. Dissociation constants of the resulting acid forms were determined.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
