Abstract
The exchange reactions between the ethylene glycol-bis(2-aminoethyl ether)-N,N,N',N'-tetraacetic acid (EGTA) complexes of Fe(III), Co(II), and Zn(II) and 4-(2-pyridylazo)resorcinol (PAR) were used to test the peformance of partial least-squares regression to calibrate the kinetic measurement of binary and ternary metal ion mixtures using a stopped-flow injection system with a diode array detector. In approach mode 1, metal ion solutions were injected directly into the flow system, where their EGTA complexes were formed. In mode 2, metal-EGTA complexes were formed prior to flow injection. From data in mode 2, it was found that displacement of EGTA was pseudo first order with rate constants of 0.012, 0.016, and 0.078 s -1 for Fe(III), Co(II), and Zn(II), respectively
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.