Abstract
AbstractThe negative slope (ΔρY+ < 0) of the Hammett‐type plot using kinetic solvent isotope effect, log kSOH/kSOD versus σ+, for methanolysis of 1‐(Y‐phenyl)ethyl chlorides is rationalized by an ion‐pair mechanism in which a solvent molecule attacks the relatively stable carbocation formed in the pre‐equilibrium.
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