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Abstract
Various types of racemic aldehydes were kinetically resolved by reaction with diethylzinc in the presence of a catalytic amount of a chiral β-amino alcohol. Kinetic resolution of racemic chloro(phenyl)acetaldehyde gave an optically active form as an unchanged substrate, which could be converted into styrene oxide in high optical purity (97.5% ee).
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Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 1
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