Abstract
AbstractBy kinetic simulation, the significant features of the mechanism of the low‐temperature photo‐oxidation of hexafluoropropene were elucidated and the rate constants for the major elementary reactions of the intermediate fluorinated peroxy and alkoxy radicals were determined through a best‐fit procedure. Comparison with analogue reactions in non‐fluorinated systems showed a significant increase in reactivity for the self‐reaction and double bond addition by peroxy radicals and β‐scission by alkoxy radicals, which are discussed in terms of fluorine substituent effects.
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