Abstract

The selective deactivation by coke deposition in the skeletal isomerization of n-butenes over a chlorinated alumina catalyst has been studied. The methodology used is based on that described in previous work (Gayubo et al., 1993), where the selective deactivation of a silica-alumina catalyst used in the double bond isomerization of n-butenes was studied. For this reaction, the triangular kinetic scheme establishes the interconversion between 1-, cis- and trans-butene.

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