Abstract

The kinetics of thermal decomposition of aluminum sulfate was studied by dynamic and isothermal thermogravimetry. The nature of the solid phases was further examined by powder x-ray diffraction. Various kinetic models such as nucleation, phase boundary movement, diffusion and the homogeneous reaction were tested. Effectiveness of integral and differential methods of data reduction was evaluated. The activation energies obtained for the sulfate decomposition, calculated from different models and methods of analysis have been compared. The results indicate that aluminum sulfate decomposition can be adequately described by phase boundary movement models with an activation energy of 235 kJ/mole. It is further observed that the alumina formed at 900°C is amorphous in nature.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.