Abstract
Extraction–oxidation desulfurization (EODS) technology would be a potential industrial application for achieving ultralow-sulfur fuel oils. A combined extraction–oxidation system for dibenzothiophene removal from model fuel with H2O2 as an oxidant, acetonitrile as an extractant, and Mo/γ-Al2O3 as a catalyst was performed in a batch reactor. To study this complex heterogeneous system, the chemical reaction and mass transfer on each phase were individually assessed. Kinetics of the EODS system for dibenzothiophene in model fuel was developed, comprising the chemical kinetic mechanism and mass transfer effects. The kinetic parameters of the kinetic model, such as the kinetic constants and apparent activation energy, were determined. The EODS system in the experimental condition is determined by both the extraction process and catalytic oxidation reaction, because the terms involving the intrinsic resistance of the chemical reaction are no more important than mass transfer resistance.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
