Abstract
This data article provides detailed guidance to obtain heterogeneous reaction rate expressions and the corresponding initial reaction rates and their application. Explanation is provided to deal with specific criteria to rule out internal and external concentration gradients, so that the usage of intrinsic catalytic data is guaranteed. Overall, the main goal is to provide an easy tool to evaluate both aforementioned results by simple plug-and-play of available reaction data.
Highlights
Kinetic modeling of heterogeneous esterification reaction using initial reaction rate analysis: data extraction and evaluation of mass transfer criteria
Explanation is provided to deal with specific criteria to rule out internal and external concentration gradients, so that the usage of intrinsic catalytic data is guaranteed
Chemical Engineering Catalysis Kinetic modelling of the heterogeneous esterification reaction of oleic acid into methyl oleate is performed on UiO-66 metal organic framework catalyst Graph Figure An amount of oleic acid (0.1 g, 0.139 g and 0.279 g) is dissolved in 1 mL methanol in a 1.5 mL GC vial, after which the UiO-66 catalyst is added at 10 mol% relative to the initial number of OA moles
Summary
Chemical Engineering Catalysis Kinetic modelling of the heterogeneous esterification reaction of oleic acid into methyl oleate is performed on UiO-66 metal organic framework catalyst Graph Figure An amount of oleic acid (0.1 g, 0.139 g and 0.279 g) is dissolved in 1 mL methanol in a 1.5 mL GC vial, after which the UiO-66 catalyst is added at 10 mol% relative to the initial number of OA moles. Experimental gas chromatographic data for oleic acid are used to calculate the corresponding conversion, which serves as input for the initial reaction rate analysis and subsequent non-linear parameter estimation procedure. Kinetic modeling of oleic acid esterification with UiO-66: from intrinsic experimental data to kinetics via elementary reaction steps, Chem. The presented data can be used as an example to set up typical heterogeneous esterification reactions by researchers working on catalytic systems with the specific purpose of kinetic modeling. Data treatment in order to calculate initial reaction rates is explained in detail with example. This has a high applicability and very easy practicability for users in the research field of heterogeneous catalysis. How to use the data is explained in this manuscript
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
