Kinetic modeling and determination role of sono/photo nanocatalyst-generated radical species on degradation of hydroquinone in aqueous solution.

Abstract

Experimental findings of sonophotocatalytic process were used in degradation of hydroquinone to assess kinetic modeling and determine the effect of various active radical species. First, the effects of three photocatalytic, sonocatalytic, and sonophotocatalytic processes were studied for hydroquinone removal to determine kinetic constants and calculate the activation energy of reactions, and then the selected process was evaluated to determine active radical species. The reactor was composed of two parts, one included ultrasonic probe (sonocatalytic part) with powers 22, 80, and 176W and the second part was the location of UV lamp (photocatalytic part) with tubular flow and power 15W. After three systems were examined and the efficient system was selected, the role of different active species such as hydroxyl radical (OH(·)), superoxide radical (O2 (·-)), hole (h(+)), electrons (e (-)), and single oxygen molecule ((1)O2) and contribution of each of them were determined in hydroquinone degradation. According to tests, the results of this study showed that sonophotocatalytic integrated method as selected system among three systems studied followed the first-order equation for hydroquinone degradation and active hydroxyl species with 45% and electron and hole with 15 and 10%, respectively, had the highest and lowest contributions to conversion of hydroquinone. The findings showed that dissolved oxygen increases the capability of active radical formation so that 28.2% of hydroquinone removal was increased under aeration compared to without aeration. Also, removal efficiency decreased 62% with N2 injection due to the withdrawal of oxygen from the sample. By adding 25Mm of sodium azide (NaN3) to stock solution, 46.5% reduction was developed because single oxygen ((1)O2) played the role of an active species. The advantages of integrated sonocatalytic and photocatalytic method are the generation of active radical species with more variety and ultimately the formation of higher amounts of powerful hydroxyl radical that increases degradation rates of refractory compounds and low-risk internal and final products. It has an appropriate performance in the degradation of refractory compounds by optimizing effective operational factors.