Abstract
A kinetic model of electrochemical deposition of composite coatings has been developed, which assumes irreversible adsorption of dispersed particles on a growing metal matrix. The irreversibility of particle adsorption is due to energy consumption required for the complete or partial removal of adsorption layers and solvate shells present on the surfaces of dispersed particles and a metal matrix, which is a necessary condition for the formation of a strong adhesive bond. The corresponding kinetic equations are derived that reflect the dependence of the content of a dispersed phase in the composite on the concentration of particles in the electrolyte, their average size and current density of metal deposition. The resulting equations are used to calculate adsorption rate constants on the basis of experimental data on the electrodeposition of nickel–titania composite coatings from an aqueous electrolyte and an electrolyte based on a choline chloride-containing deep eutectic solvent. The influence of current density on the adsorption rate constants in these electrolytes is revealed and interpreted.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
