Abstract
Kinetics of aquation of some Fe(II) Schiff base amino acid complexes was followed spectrophotometrically. The Schiff base ligands were derived from salicylaldehyde and isoleucine, leucine, serine, methionine, tryptophan, or histidine. The reaction was studied in aqueous media, aqua–propanol mixtures, and in the presence of different concentrations of KBr. Moreover, the activation parameters were calculated and discussed for structures and other physical properties observed. The reaction was acid catalyzed and the general rate equation was suggested as follows: rate = kobs [complex], where kobs = k2 [H+]. © 2010 Wiley Periodicals, Inc. Int J Chem Kinet 42: 372–379, 2010
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