Kinetic insights and pollution mitigation in waste tire pyrolysis: Targeting sulfur, nitrogen, and PAHs emissions

Abstract

Waste tires have potential to be used for generation of fuel via thermal degradation because of their non-biodegradable nature. Nevertheless, the formation of various pollutants such as sulfur-based and nitrogen-based are inevitable due to presence of nitrogen and sulfur containing compounds during waste tires production. The main purpose was to examine the effect of variating heating rates on pollutants release because heating rate is an important parameter which influences the pollutants releasing profile. Moreover, Ar and CO2 as reaction medium were used to identify their behavior for restraining the PAHs in gas phase. The present study investigates the influence of heating rates and carrier gas environment (Argon and CO2) to reduce the pollutants emission. Thermogravimetry-Mass Spectrum coupled with Fourier transform infrared spectrometer was used to evaluate the thermal degradation and pollutants formation. The major degradation of waste tires occurred between 300 and 500 ℃. The sulfur-based (H2S, CS2, COS, SO2, and CH3SH), nitrogen-based (NH3, HNCO, NO, and HCN) and 9 series of PAHs pollutants were detected. The higher heating rates promoted the pollutants emission. The degradation of compounds having sulfur content formed -SH radials and -SH helped in further release of sulfur based-pollutants. The NH3 releasing profile started after 200 ℃ and released till around 800 ℃ for 30 ⁰C/min and 40 ⁰C/min but its emission was very low after 600 ⁰C for heating rates 5 ⁰C/min, 10 ⁰C/min, and 20 ⁰C/min. The aromatic compounds fraction was more at higher heating rate due to short residence time for pyrolytic products to go through secondary reaction. The 5 ℃/min and 10 ℃/min were considered favorable heating rates in terms of achieving lowest activation energy in both gas environments. The thermodynamic parameters analysis suggested that waste tires pyrolysis was non-spontaneous and endothermic reaction as well as feedstocks showed potential to be utilized for waste conversion.