Abstract
AbstractThe extrapolated static permittivity of aqueous solutions of tetraalkylammonium bromides and azoniaspiroalkane bromides is discussed with respect to the recently predicted kinetic polarization deficiency. The experimental data are found to be not inconsistent with the theory. The large ions manifest universal hydration characteristics of organic particles, if the effect of kinetic depolarization is taken into consideration. Charged as well as neutral hydrophobic solutes seem to promote the short range molecular interactions of the water around them.
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