Kinetic crystallization of polypropylene in ternary composites based on fiber‐reinforced PP‐EPDM blends

Abstract

AbstractThe crystallization of isotactic polypropylene (iPP) in its blends with ethylene–propylene–diene terpolymer (EPDM), reinforced with different fibers, is described in this work. In particular, the effects of both the fibers and the EPDM on the crystallization kinetics and morphology of iPP are analyzed. The study was performed using differential scanning calorimetry (DSC) in dynamic and isothermal conditions and optical microscopy. It was found that all the fibers act as effective nucleant agents on iPP crystallization independently of the blend composition. The results obtained highlight the accelerating effect of the fibers and of the EPDM on the PP crystallization up to a certain EPDM percentage. The halftime of crystallization, τ1/2, and the overall crystallization rate, Kn, increase in the presence of all the fibers analyzed, showed the aramidic ones the most effective. The isothermal crystallization kinetics of ternary composites based on PP–EPDM blend matrices reinforced with different types of fibers can be modeled using the Avrami equation. On the other hand, the kinetic curves obtained under nonisothermal conditions provide a further confirmation of the nucleating action of the fibers on the PP crystallization. Optical polarizing microscopy was also used to investigate the effect of EPDM on the spherulite growth and the transcrystallinity phenomenon on the surface of the fibers. The results of such analysis showed that the transcrystallinity phenomenon is hindered at high rubber percentages. As in the case of the rate of crystallization, the highest proportion of transcrystallinity was observed in the presence of the aramidic fibers. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1063–1074, 2001