Abstract
The kinetic behavior of the free radical polymerization of N-[4-(methacryloyloxy)phenyl]-2-(4-methoxyphenyl)acetamide (OM) and N-[4-[[(4-methoxyphenyl)acetyl]oxy]phenyl]methacrylamide (MA) in solution of DMF is described. Semiempirical calculations with tretments AM1 and PM3 based on the interactions of frontier orbitals and the polarity of the π-double bond indicate that OM should polymerize at a higher rate than MA, which was experimentally demonstrated by the gravimetric study of the free readical polymerization in the temperature interval 50-150°C.
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