Kinetic and Thermodynamic Analyses of Co-Pyrolysis of Nylon-Polyethylene Pouch Wastes.

Abstract

In this study, thermogravimetric measurements of nylon-6/polyethylene double-layer pouch wastes were conducted in N2 under a constant heating-rate mode, and the multiple heating-rate results were analyzed in terms of degradation features and specific temperatures. Experimental results show that the waste pyrolysis involves one reaction stage, and all specific parameters appear to increase with the heating rate. Kinetic analysis of non-isothermal data was thoroughly performed using various isoconversional model-free methods for the calculations of the activation energy, resulting in 143~215 kJ/mol over the whole pyrolysis process. By means of the model-fitting method, the reaction mechanism model g(α) and pre-exponential factor lnk0 are concurrently determined with the aid of the linear compensation effect. With such methodology proposed, the Avrami-Erofeev kinetic model A3/2 of g(α) = [-ln(1 - α)]2/3 is found to be the most appropriate mechanism function for describing the pyrolysis of the nylon-6/polyethylene waste along with lnk0 of 23.14 to 34.26 min-1. With the Arrhenius parameters thus obtained, the predictions were made and performed very satisfactorily to correlate experimental results. Additionally, the service life and thermodynamic parameters over the entire pyrolysis process were also estimated.