Abstract
This research investigates the kinetic parameters associated with the ozonation of 2,3-, 2,4-, and 2,5-dichlorophenols (DCPs) in aqueous solutions at 25°C. The overall ozonation kinetics of each DCP was found to be first order with respect to each reactant concentration (i.e., DCP and ozone). Among the three isomers studied, the ozonation of 2,5-DCP was the fastest with the overall rate constant varying from 68,500 to 7,750,000 M−1 s−1 within a pH range of 2.1 to 5.0. The overall rate constant increased with pH because of the increase in the degree of dissociation of the DCP molecules to dichlorophenoxide ions. The electrophilic addition of ozone at the ortho and para positions of the molecular and ionic forms of the DCPs was postulated to be the likely mechanism for the degradation of the DCPs to chlorobenzenediols, monochlorophenols, chlorocyclohexadienediones, ethylacetate, heptanone, carboxylic acids, and other by-products that were detected using gas chromatograph/mass spectrometry analysis.
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